Classification and comparison of physical and chemical properties of corn stalk from three regions in China

Wang Lu, Liu Ronghou, Sun Chen, Cai Wenfei, Tao Yiwe, Yin Renzhan, Mei Yuanfei

Abstract


Abstract: Corn stalk samples from Anhui, Jiangxi and Shanghai were used as test materials. Their physical, chemical and thermo-chemical engineering characteristics were analyzed. The similarities and differences in properties of corn stalk from the three regions were determined using SIMCA-P and SPSS software in order to obtain a proper energy utilization method of corn stalk. The results show that the corn stalk from Shanghai has significant differences from the samples of Jiangxi and Anhui. In particular, the following properties of corn stalk from Shanghai such as the contents of cellulose, calcium (Ca), iron (Fe), crude ash, volatile matter, carbon (C), nitrogen (N), and oxygen (O) are significantly different from those of Jiangxi and Anhui samples (P smaller than 0.05). While other properties such as the contents of magnesium (Mg), copper (Cu), zinc (Zn), moisture, hydrogen (H), and sulfur (S) have no significant difference among samples of three regions. Compared with the corn stalk in Anhui and Jiangxi, the Shanghai samples are more suitable for the production of ethanol because of their higher ratio of cellulose to hemi-cellulose content. Because of its high content of ash and low calorific value, the Shanghai corn stalk is suitable for the gasification process instead of for direct combustion or bio-oil production. The research can provide a reference for raw material selection for biomass energy production and utilization.
Keywords: corn stalk, physical and chemical properties, bioenergy, principal components analysis, partial least squares discriminant analysis
DOI: 10.3965/j.ijabe.20140706.012

Citation: Wang L, Liu R H, Sun C, Cai W F, Tao Y W, Yin R Z, et al. Classification and comparison of physical and chemical properties of corn stalk from three regions in China. Int J Agric & Biol Eng, 2014; 7(6): 98-106.

Keywords


corn stalk, physical and chemical properties, bioenergy, principal components analysis, partial least squares discriminant analysis

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References


McKendry P. Energy production from biomass (part 2): conversion technologies. Bioresource Technology, 2002; 83: 47–54.

Bothast R J and Schlicher M A. Biotechnological processes for conversion of corn into ethanol. Appl Microbiol Biotechnol, 2005; 67(1): 19–25.

Amon T, Amon B, Kryvoruchko V, Zollitsch W, Mayer K, Gruber L. Biogas production from maize and dairy cattle manure—Influence of biomass composition on the methane yield. Agriculture, Ecosystems & Environment, 2007; 118(1-4): 173–182.

Wu C Z, Zhou Z Q, Yin X L, Yi W M. Current status of biomass energy development in China. Transactions of the CSAM, 2009; 1(40): 91–99.(in Chinese with English abstract)

Chen T, Wu C, Liu R. Steam reforming of bio-oil from rice husks fast pyrolysis for hydrogen production. Bioresour Technol, 2011; 102(19): 9236–9240.

Mullen C A, Boateng A A, Goldberg N M, Lima I M, Laird D A, Hicks K B. Bio-oil and bio-char production from corn cobs and stover by fast pyrolysis. Biomass and Bioenergy, 2010; 34(1): 67–74.

Yu F, Deng S, Chen P. Physical and chemical properties of bio-oils. Applied Biochemistry and Biotechnology, 2007; 136(140): 957–970.

Liu R H, Deng C, Wang J. Fast pyrolysis of corn straw for bio-oil production in a bench-scale fluidized bed reactor. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 2009; 32(1): 10–19.

Apaydın-Varol E, Pütün A E. Preparation and characterization of pyrolytic chars from different biomass samples. Journal of Analytical and Applied Pyrolysis, 2012; 98: 29–36.

Hou J. Related study on mechanical characteristic and physicochemical property of corn straw. Northeast Agriculture University. 2013, 6, 110p. (in Chinese with English abstract)

Huo L L, Meng H B, Tian Y S, Zhao L X, Hou S L. Experimental study on physical property of smashed crop straw. Transactions of the CSAE, 2012; 28(11): 189–195. (in Chinese with English abstract)

Tian Y S, Yao Z L, Ouyang S P, Zhao L X, Meng H B, Hou S L. Physical and chemical characterization of biomass crushed straw. Transactions of the CS AM, 2011; 9(42): 124–129. (in Chinese with English abstract)

Sluiter A, Hames B, Ruiz R, Scarlata C, Sluiter J, Templeton D, Crocker D. NREL-TP-510-42618. Determination of structural carbohydrates and lignin in biomass. National Renewable Energy Laboratory. http://www.nrel.gov. [2008-04-25], 16p.

American Society for Testing Material. E1721-01.Standard test method for determination of acid-insoluble residue in biomass. 2001-11-10.

Association of Official Analytical Chemists. 975.03. Metals in Plants and Pet Foods. 1996, 3.

American Society for Testing Material. E 1756-08. Standard test method for determination of total solids in biomass. 2008-5-1.

American Society for Testing Material. E 1755-01. Standard test method for ash in biomass. 2007-11-15.

American Society for Testing Material. E 870-82. Standard test method for analysis of wood fuels. 2006-11-1.

American Society for Testing Material. E777-08. Standard test method for carbon and hydrogen in the analysis sample of refuse-derived fuel. 2008-9-1.

Association of Official Analytical Chemists. 990.03. Protein (crude) in animal feed. AOAC official methods of analysis. 2005. pp.30–31.

Esbensen K, Geladi P. Principal component analysis. Chemometrics and Intelligent Laboratory Systems, 1987; 2: 37–52.

Kettaneh-Wold N. Analysis of mixture data with partial least squares. Chemometrics and Intelligent Laboratory Systems, 1992; 14(1–3): 57–69.

Wold S, Sjostrom M, Eriksson L. PLS-regression a basic tool of chemometrics. Chemometrics and Intelligent Laboratory Systems, 2001; 58: 109–130.

Liu R H. Present situation of biomass fast pyrolysis for bio-oil production. Journal of Shenyang Agricultural University, 2007; 2(38): 3–7. (in Chinese with English abstract)

Pasangulapati V, Ramachandriya K D, Kumar A, Wilkins M R, Jones C L, Huhnke L R. Effects of cellulose, hemicellulose and lignin on thermochemical conversion characteristics of the selected biomass. Bioresour Technol, 2012; 114: 663–671.

Lv P M, Xiong Z H, Chang J, Wu C Z, Chen Y, Zhu J X. An experimental study on biomass air-steam gasification in a fluidized bed. Bioresour Technol, 2004; 95(1): 95–101.

McKendry P. Erengy production from biomass: overview of biomass. Bioresource Technology, 2002; 83: 37–46.

Xu J J, Shen G R, Qian Z H, Huang D F, Chen E T. Spatial variability of micro-elements in agricultural soil of Chongming, Shanghai. Journal of Shanghai Jiao Tong University, 2009; 2(27): 13–18. (in Chinese with English abstract)

Wang X H, C H, Wang J, Xin F, Yang H P. Influences of mineral matters on biomass pyrolysis characteristics. Journal of Fuel Chemistry and Technology, 2008; 36(6): 679–683.

Luo Z S ,Wang Y L, Zhou J, Gu Y, Cen K. Research on biomass fast pyrolysis for liquid fuel. Biomass and Bioenergy, 2004; 26(5): 455–462.

Shen C J, Liu R H, Chen T.J. Influence of storage temperature on stability of physicochemical properties of sawdust pyrolysis bio-oil. Transactions of the CSAE, 2011; 27(2): 276–281. (in Chinese with English abstract)

Zhang S R, S B, Zhao Q G. Distribution characteristics of soil nitrogen at multi-scales in hilly region in south China. Acta Pedologica Sinica, 2007; 9(44): 885–892.

Liu R H. Biomass Energy Engineering. Beijing: Chemical Industry Press, 2009; pp. 8–12. (in Chinese)




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